Abstract

A photo-assisted electrochemical etching technique to fabricate macropores in single-crystalline gallium phosphide (GaP) with variable porosity has been developed. Scanning electron microscopy and x-ray diffraction experiments confirm that the material consists of three-dimensional, interconnected random networks with pore sizes of about 150 nanometers. Optical transmission measurements demonstrate that the nonabsorbing disordered structures strongly scatter light. The photonic strength is controlled by filling the pores with liquids of different refractive indices. Macroporous gallium phosphide filled with air has the highest scattering efficiency for visible light.

URL

https://www.science.org/doi/pdf/10.1126/science.284.5411.141

Authors

F. J. P. Schuurmans, D. Vanmaekelbergh, J. van de Lagemaat, and A. Lagendijk

Year of publication

1999

Date published

04/1999

Journal

Science

Volume

284

Pages

141-143

DOI number

10.1126/science.284.5411.141